I’ve known about John Palmer’s How to Brew website for a while. I didn’t list it here as a resource initially, though, because it’s a bit overwhleming for the beginning brewer. For your very first time, I still recommend the one page instructions produced by Beer, Beer and More Beer [PDF] - it really can be as simple as they say.
Once you’ve got the bug, though, How to Brew is a fantastic resource. It will answer most of your technical questions and really help you make the leap from beginner to intermediate and advanced with very little hassle. Highly recommended.
HowToBrew.com
Have you heard about Chugd.com, the social beer network?